Preheat your oven to 200C.
Brush both sides of each slice of bread with olive oil, and place on a baking tray. Cook for 8-10 minutes, until golden.
Meanwhile, heat a tbsp of olive oil in a pan. Once hot, add the whole padron peppers and cook for 4-5 minutes, turning regularly, until the skin is blistered. Remove onto a plate lined with kitchen paper, blot dry and sprinkle with salt.
Once the bread is cooked, top each with a suitably sized piece of jamón, followed by a whole padron pepper. Serve.